|
|
5-hydroxyanthrotainin + geranyl_diphosphate <=> previridicatumtoxin + diphosphate
|
2.5.1
|
–
|
| |
MetaCyc:
RXN-16582
|
|
|
|
Malonamoyl-CoA + malonyl-CoA + [acyl-carrier_protein] + H+ <=> 4-(3-acetyl-2,5,7,10-tetrahydroxy-4-oxo-3-hydroanthracen-2-yl)-3-oxobutanamyl-[acp] + CoA + CO2 + H2O
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-16577
|
|
|
|
4-(3-acetyl-2,5,7,10-tetrahydroxy-4-oxo-3-hydroanthracen-2-yl)-3-oxobutanamyl-[acp] <=> 12a-deshydroxy-desmethylanthrotainin + [acyl-carrier_protein] + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-16578
|
|
|
|
malonamic_acid + ATP + CoA <=> Malonamoyl-CoA + AMP + diphosphate
|
6.2.1
|
–
|
| |
MetaCyc:
RXN-16576
|
|
|
|
dimethylallyl_diphosphate + isopentenyl_diphosphate <=> geranyl_diphosphate + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
2.5.1.29
geranylgeranyl diphosphate synthase
2.5.1.67
chrysanthemyl diphosphate synthase
2.5.1.69
lavandulyl diphosphate synthase
|
–
–
–
–
–
|
| |
BRENDA:
BR47563
KEGG:
R01658
MetaCyc:
GPPSYN-RXN
SABIO-RK:
1793
|
|
|
|
S-adenosyl-L-methionine + 5-hydroxy-desmethylanthrotainin <=> 5-hydroxyanthrotainin + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-16581
|
|
|
|
12a-deshydroxy-desmethylanthrotainin + NADPH + H+ + O2 <=> desmethylanthrotainin + NADP+ + H2O
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-16579
|
|
|
|
desmethylanthrotainin + NADPH + H+ + O2 <=> 5-hydroxy-desmethylanthrotainin + NADP+ + H2O
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-16580
|
|
|
|
previridicatumtoxin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> viridicatumtoxin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-16575
|
|
